116159-22-9

Basic information

• Product Name: (E)-5-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-3-methyl-pent-2-en-1-ol
• CAS NO: 116159-22-9
• Molecular Weight: 424.656
• Mol File: 116159-22-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-5-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-3-methyl-pent-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-5-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-3-methyl-pent-2-en-1-ol(116159-22-9)
• EPA Substance Registry System: (E)-5-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-3-methyl-pent-2-en-1-ol(116159-22-9)

Safety Data

• Hazardous Substances Data: 116159-22-9(Hazardous Substances Data)

Upstream product

• 37905-03-6 8-hydroxygeranyl acetate 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 116159-24-1 3-((2R,3R)-3-{2-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-propionaldehyde 
• 116159-23-0 ((2R,3R)-3-{2-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol 

Relevant articles and documents

STUDIES IN POLYETHER SYNTHESIS USING POLYEPOXYDE CYCLISATIONS.

The acid-catalysed directed cyclisation of mono-, di-, and triepoxy t-butyl ester derivatives is used for the asymmetric synthesis of various polyether-type fragments including a C13-C27 fragment of etheromycin.The epoxide stereochemistry is set up by Sharpless epoxidation of allylic and homoallylic alcohols.