116373-38-7

Basic information

• Product Name: (2Z)-3-(2,4,6-trimethylphenyl)propenoic acid
• Synonyms: (2Z)-3-(2,4,6-trimethylphenyl)propenoic acid
• CAS NO: 116373-38-7
• Molecular Weight: 190.242
• Mol File: 116373-38-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (2Z)-3-(2,4,6-trimethylphenyl)propenoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z)-3-(2,4,6-trimethylphenyl)propenoic acid(116373-38-7)
• EPA Substance Registry System: (2Z)-3-(2,4,6-trimethylphenyl)propenoic acid(116373-38-7)

Safety Data

• Hazardous Substances Data: 116373-38-7(Hazardous Substances Data)

Upstream product

• 471-25-0 Propiolic acid 
• 108-67-8 1,3,5-trimethyl-benzene 
• 769-26-6 2-ethynyl-1,3,5-trimethylbenzene 
• 408511-61-5 2,4,6-trimethyl phenylpropiolic acid 
• 623-47-2 propynoic acid ethyl ester 
• 487-68-3 mesytaldehyde 
• 141-82-2 malonic acid 

Downstream Products

• 110795-27-2 (2E)-3-(2,4,6-trimethylphenyl)propenoic acid 
• 17804-63-6 3-(2,4,6-trimethylphenyl)propanamide 
• 7250-66-0 3-mesitylpropionic acid 

Relevant articles and documents

Alkyne hydroarylation with palladium(II) complexes bearing chelating N-heterocyclic ligands: Effect of non-coordinated nitrogens on catalyst efficiency

Palladium(II) complexes with chelating N-heterocyclic ligands bearing uncoordinated nitrogen atoms are efficient catalysts in the hydroarylation of alkynes, giving selectively trans-hydroarylation of the triple bond. The catalytic efficiency of these syst

Efficient and selective hydroarylation of propiolic acids and their esters with arenes catalyzed by a PtCl2/AgOTf system

PtCl2/AgOTf-catalyzed hydroarylation of ethyl propiolate proceeded effectively to give ethyl (2Z)-cinnamate derivatives in good to high yields, without the formation of diethyl (1E,3Z)-4-arylbuta-1,3-diene-1,3- dicarboxylates that was observed in Pd(OAc)2-catalyzed reaction. Especially, PtCl2/AgOTf-catalyzed hydroarylation of propiolic acids proceeded effectively to give (2Z)-cinnamic acids exclusively.

Electron-poor hemilabile dicationic palladium NHC complexes-synthesis, structure and catalytic activity

We present a new class of dicationic palladium NHC complexes with two carbene ligands bearing different aryl substituents and a hemilabile pyrimidyl group. They can either be synthesized from the imidazolium salts via the silver transmetalation route to a

Iron(III)-catalyzed hydroarylation of propiolic acid with activated arenes

FeCl3/AgOTf-catalyzed hydroarylation of propiolic acid with electron-rich arenes such as mesitylene, tetramethylbenzene, and pentamethylbenzene in trifluoroacetic acid proceeded to give 3-arylpropenoic acids in moderate to high yields. The same reactions with anisole and 1,4-dimethoxybenzene afforded double hydroarylation products, 3,3-diarylpropionic acids.