116525-60-1

Basic information

• Product Name: Carbamic acid, [2-(phenylethynyl)phenyl]-, methyl ester
• CAS NO: 116525-60-1
• Molecular Formula: C16H13NO2
• Molecular Weight: 251.285
• Mol File: 116525-60-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [2-(phenylethynyl)phenyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [2-(phenylethynyl)phenyl]-, methyl ester(116525-60-1)
• EPA Substance Registry System: Carbamic acid, [2-(phenylethynyl)phenyl]-, methyl ester(116525-60-1)

Safety Data

• Hazardous Substances Data: 116525-60-1(Hazardous Substances Data)

Upstream product

• 13141-38-3 2-phenylethynylaniline 
• 79-22-1 methyl chloroformate 
• 615-43-0 2-iodophenylamine 
• 536-74-3 phenylacetylene 
• 67-56-1 methanol 
• 80221-08-5 2-(2-phenylethynyl)benzamide 
• 25216-70-0 2-bromophenyl carbamic acid methyl ester 

Downstream Products

• 1347661-58-8 C₂₀H₁₈BrNO₂ 
• 1347661-60-2 3-(buta-1,3-dien-2-yl)-2-phenyl-1H-indole 
• 1347661-61-3 C₂₀H₁₇NO₂ 
• 1347661-62-4 dimethyl 4-(2-phenyl-1H-indol-3-yl)cyclohexa-1,4-diene-1,2-dicarboxylate 
• 1347661-65-7 diethyl 4-(2-phenyl-1H-indol-3-yl)pyridazine-1,2(3H,6H)-dicarboxylate 
• 1347661-67-9 6-(2-phenyl-1H-indol-3-yl)naphthalene-1,4-dione 
• 1347661-66-8 6-(2-phenyl-1H-indol-3-yl)naphthalene-1,4(5H,8H)-dione 
• 910896-41-2 methyl 2-phenyl-indole-1-carboxylate 
• 855749-10-9 methyl N-ethynyl-N-[2-(phenylethynyl)phenyl]carbamate 
• 116491-74-8 3-Allyl-2-phenyl-indole-1-carboxylic acid methyl ester 

Relevant articles and documents

Sonogashira Couplings Catalyzed by Fe Nanoparticles Containing ppm Levels of Reusable Pd, under Mild Aqueous Micellar Conditions

Nanoparticles derived from FeCl3 containing the ligand XPhos and only 500 ppm Pd effect Sonogashira couplings in water between rt and 45 °C. The entire aqueous reaction medium can be easily recycled using an "in-flask" extraction. Several tande

Synthesis of 3-[2-(1,3-butadienyl)]-1H-indoles en route to murrapanine analogue

A three-step procedure has been developed for the synthesis of 3-[2-(1,3-butadienyl)]-1H-indoles. TBAF was proved to be an effective reagent for dehydrobromination and carbomethoxy deprotection in one step to give 3-[2-(1,3-butadienyl)]-1H-indoles from the corresponding bromo-derivatives. Suitably substituted indolyl-1,3-butadiene has been successfully applied to prepare murrapanine analogue via Diels-Alder reaction.

Coupling and cycloaddition of ynamides: Homo- and Negishi coupling of tosylynamides and intramolecular [4 + 2] cycloaddition of N-(o-ethynyl)phenyl ynamides and arylynamides

N,N′-aryl- and N,N′-alkyl-buta-1,3-diyne-1,4-ditosylamides have been synthesized for the first time, in good to excellent yields, by copper-catalyzed dimerization of the corresponding N-aryl or N-alkyl tosylynamides. Negishi coupling of N-ethynylzinc tosy