1167575-44-1

Basic information

• Product Name: C₇H₁₄⁽²⁾HNO₂
• Synonyms: C₇H₁₄⁽²⁾HNO₂
• CAS NO: 1167575-44-1
• Molecular Weight: 146.194
• Mol File: 1167575-44-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₇H₁₄⁽²⁾HNO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₇H₁₄⁽²⁾HNO₂(1167575-44-1)
• EPA Substance Registry System: C₇H₁₄⁽²⁾HNO₂(1167575-44-1)

Safety Data

• Hazardous Substances Data: 1167575-44-1(Hazardous Substances Data)

Upstream product

• 1455-13-6 deuteromethanol 
• 6112-00-1 N,N-diethyl-2-diazoacetamide 

Relevant articles and documents

Ultrafast time-resolved infrared spectroscopy study of the photochemistry of N,N-diethyldiazoacetamide: rearrangement in the excited state

(Graph Presented) Ultrafast infrared spectroscopy shows that in chloroform, β-lactam is formed immediately after the laser pulse but γ-lactam is formed from both slow and fast processes. It is concluded that β-lactam is formed from the diazoamide excited state via the rearrangement in the excited state (RIES) mechanism and that γ-lactam is formed from both RIES and carbene. In methanol, both carbene decay and the rise of amide ether product are observed directly. Predictions from density functional theory calculations are consistent with these observations.