116825-35-5

Basic information

• Product Name: (2S,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-chloro-2,4-dimethyl-5-phenylsulfanyl-pentanoic acid methyl ester
• Synonyms: (2S,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-chloro-2,4-dimethyl-5-phenylsulfanyl-pentanoic acid methyl ester
• CAS NO: 116825-35-5
• Molecular Weight: 417.085
• Mol File: 116825-35-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-chloro-2,4-dimethyl-5-phenylsulfanyl-pentanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-chloro-2,4-dimethyl-5-phenylsulfanyl-pentanoic acid methyl ester(116825-35-5)
• EPA Substance Registry System: (2S,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-chloro-2,4-dimethyl-5-phenylsulfanyl-pentanoic acid methyl ester(116825-35-5)

Safety Data

• Hazardous Substances Data: 116825-35-5(Hazardous Substances Data)

Upstream product

• 116825-36-6 (2S,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5-phenylsulfanyl-pentanoic acid methyl ester 
• 56102-14-8 2-methyl-3-(phenylsulfanyl)propanal 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 116776-76-2 (2S,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5-phenylsulfanyl-pentanoic acid methyl ester 
• 108-98-5 thiophenol 
• 116776-75-1 (S)-3-((2S,3S,4S)-3-Hydroxy-2,4-dimethyl-5-phenylsulfanyl-pentanoyl)-4-isopropyl-oxazolidin-2-one 

Downstream Products

• 116776-77-3 (2S,3S,4S,5R,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-7-oxo-5-phenylsulfanyl-nonanoic acid methyl ester 
• 116840-15-4 (2S,3S,4S,5R,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-7-oxo-5-phenylsulfanyl-nonanoic acid methyl ester 
• 116805-55-1 Trifluoro-acetic acid (2E,7E)-(1R,4R,5S,6R,10S,11S,12R)-5,11-bis-(tert-butyl-dimethyl-silanyloxy)-1-ethyl-2,4,6,10,12-pentamethyl-9-oxo-13-phenylsulfanyl-trideca-2,7-dienyl ester 
• 116805-54-0 (6E,11E)-(2R,3S,4S,8R,9S,10R,13R)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-13-hydroxy-2,4,8,10,12-pentamethyl-1-phenylsulfanyl-pentadeca-6,11-dien-5-one 
• 128612-96-4 (2S,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5,5-bis-phenylsulfanyl-pentanoic acid methyl ester 

Relevant articles and documents

STUDIES IN MACROLIDE SYNTHESIS: A HIGHLY STEREOSELECTIVE SYNTHESIS OF (+)-(9S)-DIHYDROERYTHRONOLIDE A USING MACROCYCLIC STEREOCONTROL.

(+)-(9S)-Dihydroerythronolide A, 1, is prepared in 8 steps from macrolide 3 by exploiting the conformational preferences of the (5E,11E)-diene intermediate 2.The stereocontrolled introduction of the hydroxyl groups at C6, C11, and C