116972-39-5

Basic information

• Product Name: 1-hydroperoxy-1-methoxy-5-oxo-hexane
• Synonyms: 1-hydroperoxy-1-methoxy-5-oxo-hexane
• CAS NO: 116972-39-5
• Molecular Weight: 162.186
• Mol File: 116972-39-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-hydroperoxy-1-methoxy-5-oxo-hexane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-hydroperoxy-1-methoxy-5-oxo-hexane(116972-39-5)
• EPA Substance Registry System: 1-hydroperoxy-1-methoxy-5-oxo-hexane(116972-39-5)

Safety Data

• Hazardous Substances Data: 116972-39-5(Hazardous Substances Data)

Upstream product

• 159335-79-2 7-Methoxy-7-methyl-1,2-dioxepan-3-ol 
• 67-56-1 methanol 

Relevant articles and documents

Acid-catalyzed reactions of six- and seven-membered cyclic hemiperacetals and peracetals and of related bicyclic ozonides

HCl-catalyzed reactions of the hemiperacetals 3-methoxy-3-methyl-7-hydroxy-1,2-dioxepane (1a) and 3-methoxy-3-methyl-6-hydroxy-1,2-dioxane (1b) and of the related ozonides 1-methyl-6,7,8-trioxabicyclooctane (2a) and 1-methyl-5,6,7-trioxabicycloheptane (2b) gave peroxidic monocyclic (11-13), bicyclic (14), and (or) tricyclic (15) products.By contrast, reactions of the peracetals corresponding to 1a and 1b, viz., 3-methyl-3,7-dimethoxy-1,2-dioxepane (13a) and 3-methyl-3,6-dimethoxy-1,2-dioxane (13b) gave only non-peroxide products.Reactions of the persubstituted peracetals 3,6-dimethoxy-3,6-dimethyl-1,2-dioxane (25) and 3,6-dimethoxy-3-isopropyl-6-methyl-1,2-dioxane (27) also gave non-peroxidic products, which resulted from fragmentation of the carbon skeletons.