117176-08-6

Basic information

• Product Name: 4-Oxazolecarboxylicacid,4,5-dihydro-4-(1-methylethyl)-,methylester,(S)-(9CI)
• Synonyms: 4-Oxazolecarboxylicacid,4,5-dihydro-4-(1-methylethyl)-,methylester,(S)-(9CI)
• CAS NO: 117176-08-6
• Molecular Formula: C₈H₁₃NO₃
• Molecular Weight: 171.19
• Product Categories: ISOPROPYL
• Mol File: 117176-08-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Oxazolecarboxylicacid,4,5-dihydro-4-(1-methylethyl)-,methylester,(S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Oxazolecarboxylicacid,4,5-dihydro-4-(1-methylethyl)-,methylester,(S)-(9CI)(117176-08-6)
• EPA Substance Registry System: 4-Oxazolecarboxylicacid,4,5-dihydro-4-(1-methylethyl)-,methylester,(S)-(9CI)(117176-08-6)

Safety Data

• Hazardous Substances Data: 117176-08-6(Hazardous Substances Data)

Upstream product

• 63472-88-8 methyl 2-isocyano-3-methylbutyrate 

Downstream Products

• 117176-12-2 N,O-dibenzoyl-α-isopropylserine methyl ester 

Relevant articles and documents

ASYMMETRIC ALDOL REACTION OF α-ISOCYANOCARBOXYLATES WITH PARAFORMALDEHYDE CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-GOLD(I) COMPLEXES: CATALYTIC ASYMMETRIC SYNTHESIS OF α-ALKYLSERINES

Aldol reaction of methyl α-isocyanocarboxylates (CNCH(R)COOMe: R=H, Me, Et, i-Pr, Ph) with paraformaldehyde in the presence of 1 molpercent of a chiral (aminoalkyl)ferrocenylphosphine-gold(I) complex gave optically active 4-alkyl-2-oxazoline-4-carboxylates (up to 83percent ee) which were readily hydrolyzed to α-alkylserines.