117285-67-3

Basic information

• Product Name: methyl 3-(2-acetoxy-4-methoxyphenyl)propanoate
• Synonyms: methyl 3-(2-acetoxy-4-methoxyphenyl)propanoate
• CAS NO: 117285-67-3
• Molecular Weight: 252.267
• Mol File: 117285-67-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 3-(2-acetoxy-4-methoxyphenyl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(2-acetoxy-4-methoxyphenyl)propanoate(117285-67-3)
• EPA Substance Registry System: methyl 3-(2-acetoxy-4-methoxyphenyl)propanoate(117285-67-3)

Safety Data

• Hazardous Substances Data: 117285-67-3(Hazardous Substances Data)

Upstream product

• 93198-68-6 (E)-methyl 2’-hydroxy-4’-methoxycinnamate 
• 531-59-9 7-methoxycoumarin 
• 117285-66-2 methyl 2'-acetoxy-4'-methoxycinnamate 
• 144582-47-8 methyl 2'-acetoxy-4'-methoxycinnamate 

Downstream Products

• 117285-77-5 methyl 3-(5-acetyl-2-hydroxy-4-methoxyphenyl)propanoate 
• 144582-51-4 methyl 3-(5-acetyl-2,4-dihydroxyphenyl)propanoate 

Relevant articles and documents

Syntheses of 6-acylcoumarins via highly regioselective fries rearrangements. Total syntheses of the linear acylated coumarins geijerin and dehydrogeijerin

Methyl 3-(2-acyloxy-4-methoxyphenyl)propanoates (7), prepared in high yield from 7-methoxycoumarin are key intermediates in general and efficient syntheses of 6-acylcoumarins. Under standard Fries rearrangement conditions (7) undergo highly regioselective