117370-99-7Relevant articles and documents
An efficient synthesis of selectively functionalized D-rhamnose derivatives
Zunk, Matthew,Kiefel, Milton J.
, p. 1296 - 1299 (2011)
D-Rhamnose is an important component of bacterial lipopolysaccharides. This paper describes a short and highly efficient synthesis of D-rhamnose from D-mannose. The synthesis of selectively C-4 modified d-rhamnosides and 6-deoxy-D-talosides as potential building blocks for complex oligosaccharide synthesis is also discussed.
A SYNTHESIS OF AMMONIUM 3-DEOXY-D-MANNO-2-OCTULOSONATE (AMMONIUM KDO) FROM D-MANNOSE VIA COBALOXIME-MEDIATED RADICAL ALKYL-ALKENYL CROSS COUPLING
Branchaud, Bruce P.,Meier, Mark S.
, p. 3191 - 3194 (2007/10/02)
We report a synthesis of the ammonium salt of the 8-carbon monosaccharide 3-deoxy-D-manno-2-octulosonic acid (KDO) starting from D-mannose.The key C-C bond construction in our synthetic strategy is a novel alkyl cobaloxim mediated radical alkyl-alkenyl cr