117416-50-9Relevant articles and documents
A convenient and inexpensive conversion of an aziridine to an oxazolidinone
Hancock, Matthew T.,Pinhas, Allan R.
, p. 5457 - 5460 (2003)
The conversion of an aziridine to the corresponding oxazolidinone using only carbon dioxide and a catalytic amount of lithium iodide is discussed. In all cases, either no reaction occurred or a high yield of product was obtained. HMPA has been added to th
Preparation of 2-oxazolidinones by intramolecular nucleophilic substitution
Van Delft, Floris L.,Timmers, Cornelis M.,Van Der Marel, Gijs A.,Van Boom, Jacques H.
, p. 450 - 454 (2007/10/03)
Treatment of N-alkoxycarbonyl, N-benzyl protected β-amino alcohols with triphenylphosphine and hexachloroethane in 1,2-dichloroethane induces cyclization to 2-oxazolidinones, which are formed by intramolecular attack with inversion of configuration at the secondary alcohol. In contrast, mono N-substituted alkyl carbamates undergo chlorination under the same conditions.
A GENERAL METHOD FOR STEREO- AND REGIO-SPECIFIC OXYAMINATION OF OLEFINS
Das, Jagabandhu
, p. 907 - 916 (2007/10/02)
A new synthetic method for stereo and regioscpecific oxyamination of olefins is described.
