117437-02-2

Basic information

• Product Name: bis{μ-(acetyl-2-dimethyl-4,5-phenolato-O,O)}hexachlorodietain
• CAS NO: 117437-02-2
• Molecular Weight: 776.53
• Mol File: 117437-02-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis{μ-(acetyl-2-dimethyl-4,5-phenolato-O,O)}hexachlorodietain(CAS DataBase Reference)
• NIST Chemistry Reference: bis{μ-(acetyl-2-dimethyl-4,5-phenolato-O,O)}hexachlorodietain(117437-02-2)
• EPA Substance Registry System: bis{μ-(acetyl-2-dimethyl-4,5-phenolato-O,O)}hexachlorodietain(117437-02-2)

Safety Data

• Hazardous Substances Data: 117437-02-2(Hazardous Substances Data)

Upstream product

• 22618-23-1 3,4-dimethylphenyl acetate 
• 7646-78-8 tin(IV) chloride 

Relevant articles and documents

Synthesis and Characterization of a New Class of Flavylium Salts; a Facile Route to the 2-(2-Acetoxyphenyl)-4-methylidene-4H-1-benzopyran Derivatives. X-Ray Crystal Structure of 2-(2-Acetoxy-5-methylphenyl)-4,6-dimethyl-1-benzopyranylium Pentachlorostannate: Supporting Evidence of Chl...

Several mixtures of compounds 1 and 2 were synthesized from SnCl4 and p-substituted aryl acetates.Separation of 1/2 was achieved either by treatment of the mixture with MeCN prviding the pure complex 1 or by reaction with MeCOCl leading selectively to a new class of flavylium salts 3 or 4.The structure of 2-(2-acetoxy-5-methylphenyl)-4,6-dimethyl-1-benzopyranylium pentachlorostannate (3a) was determined by single-crystal X-ray diffraction.The Sn-atoms are hexacoordinated in the dimeric unit Sn2Cl102- through Cl bridging.Furthermore, we report the easy preparation of 1-benzopyran derivatives starting from the salts 3.