117712-89-7

Basic information

• Product Name: (5R)-5-methyl-1-((1R)-1-methyl-2-propen-1-yl)-2-(2-propen-2-yl)cyclohexene
• Synonyms: (5R)-5-methyl-1-((1R)-1-methyl-2-propen-1-yl)-2-(2-propen-2-yl)cyclohexene
• CAS NO: 117712-89-7
• Molecular Weight: 190.329
• Mol File: 117712-89-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (5R)-5-methyl-1-((1R)-1-methyl-2-propen-1-yl)-2-(2-propen-2-yl)cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (5R)-5-methyl-1-((1R)-1-methyl-2-propen-1-yl)-2-(2-propen-2-yl)cyclohexene(117712-89-7)
• EPA Substance Registry System: (5R)-5-methyl-1-((1R)-1-methyl-2-propen-1-yl)-2-(2-propen-2-yl)cyclohexene(117712-89-7)

Safety Data

• Hazardous Substances Data: 117712-89-7(Hazardous Substances Data)

Upstream product

• 4894-61-5 trans-but-2-enyl chloride 
• 89-82-7 pulegone 
• 112197-53-2 (+)-(1S,5R)-1-((1R)-1-methyl-2-propen-1-yl)-2-(1-methylethylidene)-5-methylcyclohexanol 

Relevant articles and documents

Palladium-mediated cyclization of 1,5-hexadien-3-ols to 1-methyl-1,3-cyclopentadienes

Treatment of 1,5-hexadien-3-ols in acetic acid by Pd(o) [Pd(PPh3)4] led to 1-methyl-1,3-cyclopentadienes. Cyclization is improved by the presence of catalytic amount of trifluoroacetic acid. Mechanism is discussed from the observed r

Importance of Structure of α,β-Ethylenic Ketones during Their Reductive Coupling Promoted by the TiCl4-Mg Reagent

In most cases, the reductive coupling of α,β-ethylenic ketones by the TiCl4-Mg reagent leads to 1,3,5-trienes and bisallylic pinacols.Some α,β-enones of s-cis configuration, such as (+)-pulegone, show a particular reactivity: formation of dihydro ketones in the presence of tert-butyl alcohol and reductive alkylation with allylic halides or benzyl bromide.Results are accordance with a polymeric structure for the native low-valent titanium species, and in the case of some s-cis-enones, they can be explained by the intervention of a oxametallacyclopentene.