117912-00-2Relevant articles and documents
Three's company: Co-crystallization of a self-assembled S4 metallacyclophane with two diastereomeric metallacycle intermediates
Lindquist, Nathan R.,Carter, Timothy G.,Cangelosi, Virginia M.,Zakharov, Lev N.,Johnson, Darren W.
, p. 3505 - 3507 (2010)
Three discrete supramolecular self-assembled arsenic(iii) complexes including an unusual S4-symmetric tetranuclear [As4L 2Cl4] metallacyclophane and two diastereomeric cis/trans-[As2LCl2] metallacycle intermediates co-crystallize within a single crystal lattice.
Synthesis, Structure, and Properties of Triple-Layered Naphthalenophane
Otsubo, Tetsuo,Aso, Yoshio,Ogura, Fumio,Misumi, Soichi,Kawamoto, Atsushi,Tanaka, Jiro
, p. 164 - 170 (2007/10/02)
The title compound was synthesized in a similar manner to a simple access to triple-layered paracyclophane.Its structure was elucidated by X-ray crystallographic analysis.The outer naphthalene rings are bent into a boat form and the inner naphthalene ring is bent into a twist form.These naphthalenes are stacked in layers within van der Waals contact.Therefore, there is a strong transannular ?-electronic interaction between them, which brings about characteristic bathochromism, hyperchromism, and broadening in the electronic spectrum.These effects are more prominent than those of the double-layered homologue.
