117971-12-7

Basic information

• Product Name: (Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene
• Synonyms: (Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene
• CAS NO: 117971-12-7
• Molecular Weight: 188.149
• Mol File: 117971-12-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene(117971-12-7)
• EPA Substance Registry System: (Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene(117971-12-7)

Safety Data

• Hazardous Substances Data: 117971-12-7(Hazardous Substances Data)

Upstream product

• 661-54-1 3,3,3-trifluoroprop-1-yne 
• 108-95-2 phenol 
• 102687-65-0 trans-1-chloro-3,3,3-trifluoropropene 
• 2730-62-3 2-chloro-1,1,1-trifluoropropene 

Relevant articles and documents

Reaction of substituted phenols and alcohols with (E)-1-chloro-3,3,3-trifluoropropene (HFCO-1233zd)

Simple and convenient one-pot procedures for the preparation of ArOCH=CHCF3, ROCH=CHCF3 and CF3CH=CHOArOCH = CHCF3 starting from the industrial product HFCO-1233zd (CF3CH=CHCl) are presented. These syntheses involve the reaction of 1233zd with phenols and alcohols in the presence of potassium hydroxide in DMF or pyridine solvent at elevated temperatures.

REGIOSELECTIVITY IN ADDITION REACTIONS OF SOME BINUCLEOPHILIC REAGENTS TO TRIFLUOROMETHYLACETYLENE

In the reactions of hydrazine hydrate, ethylenediamine, o-phenylenediamine, ethylene glycol, monothioglycol, and dithioglycol with trifluoromethylacetylene addition takes place regioselectively with or without subsequent cyclization.The β-carbon atom of t