118095-15-1

Basic information

• Product Name: 1,3-dimethyl-2-(p-tolyloxy)benzene
• Synonyms: 1,3-dimethyl-2-(p-tolyloxy)benzene
• CAS NO: 118095-15-1
• Molecular Weight: 212.291
• Mol File: 118095-15-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-dimethyl-2-(p-tolyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-dimethyl-2-(p-tolyloxy)benzene(118095-15-1)
• EPA Substance Registry System: 1,3-dimethyl-2-(p-tolyloxy)benzene(118095-15-1)

Safety Data

• Hazardous Substances Data: 118095-15-1(Hazardous Substances Data)

Upstream product

• 576-26-1 2.6-dimethylphenol 
• 624-31-7 4-tolyl iodide 
• 5720-05-8 4-methylphenylboronic acid 

Relevant articles and documents

Facile synthesis of 9-azajulolidine and its application to post-Ullmann reactions

This Letter describes the efficient synthesis of 9-azajulolidine from readily available reagents and its utilization as an effective electron-rich ligand for post-Ullmann-type reactions, that is, for C(aryl)-heteroatom (N, O, S) bond formation reactions, with dramatically enhanced reaction rates.

Copper mediated formation of carbon-heteroatom bonds using organoboron reagents and ultrasound

This report summarizes research efforts focused on copper acetate mediated reactions to form new carbon-heteroatom bonds using organoboron reagents under ultrasound irradiation. The method involves the application of ultrasound irradiation to the Chan-Evans-Lam reaction to achieve O-arylation of phenols, N-arylation of anilines and indoles, and S-arylation of thiols. Ultrasound irradiation was found to decrease reaction times from 72 hours to 4 hours while improving the product yields an average of 20%.1 Representative C-O, C-N, and C-S coupling reactions were successfully scaled-up from the milligram to gram levels while maintaining good product yields offering potential applications in industrial processes.