118132-05-1Relevant articles and documents
Reactive conducting thiepin polymers
Song, Changsik,Swager, Timothy M.
scheme or table, p. 999 - 1005 (2010/04/06)
(Chemical Equation Presented) We report the design and synthesis of annulated thiepins designed to undergo bent-to-planar transformation driven by aromatization under electrochemical control. Thiepins are conjugated seven-membered ring systems with a thioether in the macrocycle. We synthesized thermally stable thiepins that are electropolymerizable to give rise to thiepin-containing electroactive polymers. Extended thiepin systems undergo sulfur extrusion with oxidation, and this feature has utility in peroxide sensing. 2009 American Chemical Society.