1181403-95-1Relevant articles and documents
Controlling the charge transfer in phenylene-bridged borylene-amine π-conjugated systems
Pron, Agnieszka,Zhou, Gang,Norouzi-Arasi, Hassan,Baumgarten, Martin,Muellen, Klaus
supporting information; experimental part, p. 3550 - 3553 (2011/02/22)
Image Presented Novel boron-nitrogen-containing π-conjugated compounds 3,3′- and 4,4′-((2,4,6-triisopropylphenyl)borylene)bis(N, N-diarylbenzenamine) (1-2), m- and p-phenylene bridged to the boron center, respectively, have been synthesized and characterized. Optical studies by means of UV-vis absorption and emission measurements as well as DFT calculations reveal a different charge transfer behavior between the para series and the meta series at ground and excited states.