118272-45-0

Basic information

• Product Name: 9-(2',6',6'-trimethyl-1'-cyclohexen-1'-yl)-3,7-dimethyl-1-<(tert-butyldimethylsilyl)oxy>-(2E,5E,8E)-nona-2,5,8-triene-4,7-diol
• CAS NO: 118272-45-0
• Molecular Weight: 434.735
• Mol File: 118272-45-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 9-(2',6',6'-trimethyl-1'-cyclohexen-1'-yl)-3,7-dimethyl-1-<(tert-butyldimethylsilyl)oxy>-(2E,5E,8E)-nona-2,5,8-triene-4,7-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(2',6',6'-trimethyl-1'-cyclohexen-1'-yl)-3,7-dimethyl-1-<(tert-butyldimethylsilyl)oxy>-(2E,5E,8E)-nona-2,5,8-triene-4,7-diol(118272-45-0)
• EPA Substance Registry System: 9-(2',6',6'-trimethyl-1'-cyclohexen-1'-yl)-3,7-dimethyl-1-<(tert-butyldimethylsilyl)oxy>-(2E,5E,8E)-nona-2,5,8-triene-4,7-diol(118272-45-0)

Safety Data

• Hazardous Substances Data: 118272-45-0(Hazardous Substances Data)

Upstream product

• 17974-59-3 (7E)-9-ethynyl-β-ionol 
• 79-77-6 (E)-β-ionone 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 95286-43-4 ethyl 9-(2',6',6'-trimethyl-1'-cyclohexen-1'-yl)-3,7-dimethyl-4,7-dihydroxy-(2E,8E)-nona-2,8-dien-5-ynoate 
• 118304-71-5 (2E,8E)-3,7-Dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,8-dien-5-yne-1,4,7-triol 
• 83803-81-0 ethyl (E/Z)-4,4-dimethoxy-3-methylbut-2-enoate 
• 62054-49-3 ethyl (E)-3-formyl-2-butenoate 
• 118282-96-5 (1E,7E)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-1,7-dien-4-yne-3,6-diol 
• 96928-85-7 methyl (Z)-3-methyl-4-oxo-2-butenoate 
• 40834-42-2 5-hydroxy-4-methyl-5H-furan-2-one 
• 118282-96-5 (1E,7Z)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-1,7-dien-4-yne-3,6-diol 
• 118304-63-5 methyl 9-(2',6',6'-trimethyl-1'-cyclohexen-1'-yl)-4,7-dihydroxy-3,7-dimethyl-(2Z,8E)-nona-2,8-dien-5-ynoate 

Downstream Products

• 118304-54-4 tert-butyldimethylsilyl Δ¹³-(Z)-retinyl ether 
• 118353-70-1 tBDMS-retinol 
• 68-26-8 RETINOL 
• 302-79-4 all-trans-retinoic-acid 
• 116-31-4 all-trans-Retinal 

Relevant articles and documents

Synthesis of New Aromatic Retinoid Analogues by Low-Valent Titanium Induced Reductive Elimination

The low-valent titanium reductive elimination reaction, already applied to the stereospecific synthesis of vitamin A and 13-cis-retinol, was used to prepare several retinoic acid analogues in the all-trans configuration or in the 13-cis configuration.This highly stereospecific trans-diene formation allowed an improved synthesis of the title compounds without any purification of the intermediates before the final stage.

Highly stereoselective synthesis of 13-cis retinoic acid by low-valent titanium induced reductive elimination

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