118354-45-3

Basic information

• Product Name: 2-((Z)-3,4-Dimethyl-6-trimethylsilanyl-hex-4-enyl)-cyclohex-2-enone
• CAS NO: 118354-45-3
• Molecular Weight: 278.51
• Mol File: 118354-45-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-((Z)-3,4-Dimethyl-6-trimethylsilanyl-hex-4-enyl)-cyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((Z)-3,4-Dimethyl-6-trimethylsilanyl-hex-4-enyl)-cyclohex-2-enone(118354-45-3)
• EPA Substance Registry System: 2-((Z)-3,4-Dimethyl-6-trimethylsilanyl-hex-4-enyl)-cyclohex-2-enone(118354-45-3)

Safety Data

• Hazardous Substances Data: 118354-45-3(Hazardous Substances Data)

Upstream product

• 70156-98-8 6-bromo-1,4-dioxaspiro[4,5]dec-6-ene 
• 94852-05-8 ((E)-6-Iodo-3,4-dimethyl-hex-2-enyl)-trimethyl-silane 
• 930-68-7 cyclohexenone 
• 497-03-0 2-methylbut-2-enal 
• 50870-61-6 2-bromocyclohex-2-en-1-one 
• 211734-37-1 (E)-3-Methyl-1-trimethylsilanyl-pent-3-en-2-ol 
• 211734-39-3 (E)-3,4-Dimethyl-6-trimethylsilanyl-hex-4-en-1-ol 
• 211734-38-2 (E)-3,4-Dimethyl-6-trimethylsilanyl-hex-4-enal 

Downstream Products

• 55890-21-6 linaridal 

Relevant articles and documents

REMARKABLE STEREOCONTROL OBSERVED IN THE RING FORMATION BY INTRAMOLECULAR HOSOMI-SAKURAI REACTION

The cyclization of 2-(3',4'-dimethyl-6'-trimethylsilyl-4'-hexenyl)-2-cyclohexenone with TiCl4 afforded stereospecifically 6α,7α-dimethyl-6β-vinyl-5βH-1-decalone derivate and the two-fold diastereoselection involved is reasoned in terms of orientation control and folding strain control.