118466-21-0Relevant articles and documents
Conjugated dyes carrying N, N-dialkylamino and ketone groups: One-component visible light Norrish type II photoinitiators
Ding, Ge,Jing, Chuan,Qin, Xiaozhuan,Gong, Yulong,Zhang, Xueping,Zhang, Shengtao,Luo, Ziping,Li, Hongru,Gao, Fang
, p. 456 - 467 (2017)
This work presents new conjugated dyes carrying N, N-dialkylamino and ketone groups for using as one-component Norrish type II visible light photoinitiators. The novel dyes without ketone group were also synthesized to compose two-component visible light photoinitiators for comparisons. The target dyes show the remarkable absorption in visible light region. Photo-differential scanning calorimetry was employed to study visible light photoinitiating polymerization kinetics of methyl methacrylate by new one-component photoinitiators and two-component photoinitiators respectively. The results suggest that the one-component photoinitiators showed much more efficient photoinitiating polymerization of methyl methacrylate than the two-component photoinitiating systems under visible light irradiation. The molecular weight of visible light photopolymer produced by the new photoinitiators was determined. The visible light photoinitiating mechanism of the one-component photoinitiators was studied by absorption and emission spectra, electron spin resonance spectra and cyclic voltammograms analysis.
STILBENE-BASED REACTIVE COMPOUNDS, POLYMERIC MATRICES FORMED THEREFROM, AND ARTICLES VISUALIZABLE BY FLUORESCENCE
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Page/Page column, (2014/06/24)
The invention is directed to latent reactive and polymerizable derivatives of fluorescent stilbene-based compounds. The compounds can be used to provide articles with a fluorescence property, such as medical devices (e.g., catheters). The fluorescent compounds can be used in association with polymers, or can be incorporated into polymers, and the polymers used in a coating composition on the article surface. The compounds allow for visual or machine inspection of coating properties such as uniformity of coverage.
Two-photon optical properties of novel branched conjugated derivatives carrying benzophenone moiety with various electron donor-acceptor substituent groups
Li, Hongru,Yang, Long,Liu, Jian,Wang, Chunfeng,Gao, Fang,Zhang, Shengtao
experimental part, p. 393 - 407 (2012/04/23)
This paper presents a range of novel new branched conjugated dyes containing benzophenone moiety. As compared with those of 4-(p-benzoyl-styrene) yl-4′-(styrene)yl-triphenylamine (C1) and 4-(p-benzoyl-styrene)yl- 4′-3,4,5-trimethoxyl-styrene)yl-triphenylamine (C2), the maximal linear absorption and emission wavelength of 4-(p-benzoyl-styrene)yl-4′- (p′-nitro-styrene)yl-triphenylamine (C3) displays red-shifted remarkably, While the fluorescence quantum yields of C3 are lower than those of C1 and C2 in various solvents. The fluorescence lifetimes of the derivatives were measured, and radiative and non-radiative transition constants of the derivatives were calculated. Two-photon absorption (TPA) optical data of the derivatives were measured by Ti:sapphire femtosecond laser tuning from 720 to 880 nm at intervals of 20 nm. TPA induced fluorescence emission of C3 is red-shifted with respected to that of C1 and C2. TPA cross sections of C3 are larger than those of C1 and C2 in various excited laser frequencies. TPA cross section of C2 and C3 are much larger than those of 3,4,5-(trimethoxylstyrene)yl-triphenylamine (C4) and 4-(p-nitrostyrene)yl-triphenylamine (C5) respectively under various near-IR Ti:sapphire femtosecond laser wavelength. C1 and C2 show similar one- and two- photon optical nature. Geometry optimization with ab initio method confirms that C3 has different electron density distribution, the energy levels in frontier orbitals, the dipole moment changes, the absorption and emission spectroscopy from those of C1 and C2. The cyclic voltammograms of the derivatives were detected in methylene chloride at various scan rates, and the energy of frontier orbials were estimated further from the redox potentials.