1186047-46-0

Basic information

• Product Name: [Ru(η2-H2C=C=CH2)(CO)2(PPh3)2]
• Synonyms: [Ru(η2-H2C=C=CH2)(CO)2(PPh3)2]
• CAS NO: 1186047-46-0
• Molecular Weight: 721.737
• Mol File: 1186047-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(η2-H2C=C=CH2)(CO)2(PPh3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(η2-H2C=C=CH2)(CO)2(PPh3)2](1186047-46-0)
• EPA Substance Registry System: [Ru(η2-H2C=C=CH2)(CO)2(PPh3)2](1186047-46-0)

Safety Data

• Hazardous Substances Data: 1186047-46-0(Hazardous Substances Data)

Upstream product

• 35880-54-7 {ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)} 
• 463-49-0 1,2-propanediene 

Downstream Products

• 14564-35-3 cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) 

Relevant articles and documents

Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: A phosphinoallene complex

[Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a complex of a phosphonioallene on the basis of crystallographic data for [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]2Br(PF6) and a comparison of spectroscopic data with those for the simple allene complex [Ru(γ2-H2C=C=CH2)(CO) 2(PPh3)2].