1186634-65-0

Basic information

• Product Name: 2-bromocinnamyl methyl carbonate
• Synonyms: 2-bromocinnamyl methyl carbonate
• CAS NO: 1186634-65-0
• Molecular Weight: 271.111
• Mol File: 1186634-65-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-bromocinnamyl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromocinnamyl methyl carbonate(1186634-65-0)
• EPA Substance Registry System: 2-bromocinnamyl methyl carbonate(1186634-65-0)

Safety Data

• Hazardous Substances Data: 1186634-65-0(Hazardous Substances Data)

Upstream product

• 56984-71-5 (E:Z)-3-(2-bromophenyl)prop-2-en-1-ol 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1402406-45-4 (R)-1-bromo-2-(1-nitrobut-3-en-2-yl)benzene 

Relevant articles and documents

Iridium-Catalyzed Propenylation Reactions for the Synthesis of 4-Pyridone Derivatives

Herein we report an iridium-catalyzed propenylation reaction of allylic carbonates with 4-hydroxypyridine derivatives. The process efficiently provides 4-pyridone derivatives with high stereoselectivities under mild conditions. The products could constitute valuable building blocks for the synthesis of natural products and other bioactive molecules. Preliminary mechanistic studies indicated that a tandem allylic substitution/isomerization reaction occurs to afford the propenylation products. (Figure presented.).