1186689-43-9Relevant articles and documents
Palladium-catalyzed C-H arylation using aryltrifluoroborates in conjunction with a MnIII oxidant under mild conditions
Seigerman, Cydney K.,Micyus, Tiffiny M.,Neufeldt, Sharon R.,Sanford, Melanie S.
, p. 5580 - 5587 (2013/06/27)
This paper describes the development of a mild Pd-catalyzed C-H arylation reaction using potassium aryltrifluoroborates in conjunction with Mn(OAc) 3 as the oxidant. The scope of this transformation is explored with a variety of different aryltrifluoroborates and arylpyridine substrates. Preliminary mechanistic studies suggest that the reaction proceeds via a high-valent Pd mechanism with C-H activation occurring at or before the rate determining step.
