1187772-46-8

Basic information

• Product Name: 2-naphthalen-1-ylethynyl-5-phenyl-oxazole
• Synonyms: 2-naphthalen-1-ylethynyl-5-phenyl-oxazole
• CAS NO: 1187772-46-8
• Molecular Weight: 295.34
• Mol File: 1187772-46-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-naphthalen-1-ylethynyl-5-phenyl-oxazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-naphthalen-1-ylethynyl-5-phenyl-oxazole(1187772-46-8)
• EPA Substance Registry System: 2-naphthalen-1-ylethynyl-5-phenyl-oxazole(1187772-46-8)

Safety Data

• Hazardous Substances Data: 1187772-46-8(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 1006-68-4 5-phenyloxazole 
• 77295-63-7 1-(2,2-dibromovinyl)naphthalene 
• 77295-80-8 1-(2-bromoethynyl)naphthalene 

Relevant articles and documents

Synthesis and evaluation of photophysical properties of Series of π-conjugated oxazole dyes

Incorporation of π-conjugated spacers at the 2 or 5 position of a 2,5-disubstitutedaryloxazole led to new series of fluorescent dyes. They show emissions from visible to 700 nm along with significant Stokes shift up to 208 nm and a strong solvatochromic fluorescence. These compounds are easily accessible in one step through direct C-H bond functionalization.

Copper as a powerful catalyst in the direct alkynylation of azoles

[Chemical equation presented] Copper-bottomed catalysis! The direct alkynylation of azoles through a copper-based C - H bond activation, using alkynylbromides as the coupling partner, has been developed (see scheme). The method is very rapid, is functional-group tolerant, and provides a straightforward entry to diverse alkynyl heterocycles that is complementry to the Sonogashira reaction.