1187790-36-8

Basic information

• Product Name: N,N-bis(diphenylphosphino)-4-isopropylaniline
• Synonyms: N,N-bis(diphenylphosphino)-4-isopropylaniline
• CAS NO: 1187790-36-8
• Molecular Weight: 503.563
• Mol File: 1187790-36-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N,N-bis(diphenylphosphino)-4-isopropylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis(diphenylphosphino)-4-isopropylaniline(1187790-36-8)
• EPA Substance Registry System: N,N-bis(diphenylphosphino)-4-isopropylaniline(1187790-36-8)

Safety Data

• Hazardous Substances Data: 1187790-36-8(Hazardous Substances Data)

Upstream product

• 99-88-7 4-Isopropylaniline 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 1428247-00-0 [rhodium(I)((Ph₂P)2N-C₆H₄-4-CH(CH₃)2)(1,5-cyclooctadiene)](tetrafluoroborate) 
• 1187790-46-0 dichloro[N,N-bis(diphenylphosphino)-4-ispopropylaniline]platinum(II) 
• 1187790-44-8 dichloro[N,N-bis(diphenylphosphino)-4-isopropylaniline]palladium(II) 
• 1256653-31-2 [RuCp(*)((Ph₂P)2N-C₆H₄-4-CH(CH₃)2)Cl] 
• 1256653-30-1 [Ru((Ph2P)2N-C6H4-4-CH(CH3)2)(η6-p-cymene)Cl]Cl 

Relevant articles and documents

Rhodium-catalyzed transfer hydrogenation with functionalized bis(phosphino)amine ligands

A series of novel cationic mononuclear rhodium(I) complexes with the P-N-P ligands have been prepared starting from the complex [Rh(cod) 2]BF4. The structural elucidation of the complexes was carried out by elemental analyses, IR and multinuclear NMR spectroscopic data. Furthermore, the complexes were applied to the transfer hydrogenation of ketones in the presence of 2-propanol as the hydrogen source. Catalytic studies showed that all complexes are excellent catalytic precursors for the transfer hydrogenation of aryl alkyl ketones in 0.1 M iso-PrOH solution. Especially, [Rh((Ph2P)2N-C6H4-4-CH(CH 3)2)(cod)]BF4 acts as an excellent catalyst giving the corresponding alcohols in excellent conversion up to 99% (TOF ≤ 1980 h-1).

Ruthenium-catalyzed transfer hydrogenation of aromatic ketones with aminophosphine or bis(phosphino)amine ligands derived from isopropyl substituted anilines

A series of new highly active Ru(II) complexes with two new (N-diphenylphosphino)isopropylanilines, having an isopropyl substituent at carbon 2- (1) or 2,6- (2) and two new bis(diphenylphosphino)isopropylanilines, having an isopropyl substituent at carbon