119197-56-7

Basic information

• Product Name: 7-acetoxy-4-acetoxymethyl-2-heptanone
• Synonyms: 7-acetoxy-4-acetoxymethyl-2-heptanone
• CAS NO: 119197-56-7
• Molecular Weight: 244.288
• Mol File: 119197-56-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 7-acetoxy-4-acetoxymethyl-2-heptanone(CAS DataBase Reference)
• NIST Chemistry Reference: 7-acetoxy-4-acetoxymethyl-2-heptanone(119197-56-7)
• EPA Substance Registry System: 7-acetoxy-4-acetoxymethyl-2-heptanone(119197-56-7)

Safety Data

• Hazardous Substances Data: 119197-56-7(Hazardous Substances Data)

Upstream product

• 75-07-0 acetaldehyde 
• 591-87-7 Allyl acetate 

Relevant articles and documents

UV-LIGHT- AND RADIATION-INITIATED ADDITION OF ACETALDEHYDE TO ALLYL ALKANOATES

UV-light- and γ-60Co-initiated addition of acetaldehyde to allyl formate (I) and allyl acetate (II) yielded the 1:1 adducts - 4-oxopentyl formate (III) and 4-oxopentyl acetate (IV), respectively, together with the 1:2 telomers - 7-formyloxy-4-formyloxymethyl-2-heptanone (V) and 7-acetoxy-4-acetoxymethyl-2-heptanone (VI).The initial radiation yields are: G(III) = 200.8, G(IV) = 211.3, G(V) = 39.5, G(VI) = 37.9.Base-catalyzed transesterification of oxopentyl alkanoates III and IV afforded 5-hydroxy-2-pentanone (XIV), the same reaction of dialkylalkanoates VI and VII gave 5-hydroxy-4-hydroxymethyl-2-heptanone (XV).