1192284-22-2Relevant articles and documents
Synthesis and nonlinear optical properties of novel polyester containing tricyanovinylthiophene with enhanced thermal stability of second harmonic generation
Lee, Ga-Young,No, Hyo Jin,Lee, Ju-Yeon
, p. 196 - 203 (2009)
A novel Y-type polyester (7) containing 1-(2,4-dioxyethoxy)phenyl-2-{5-(1, 2,2- tricyanovinyl)-2-thiophenyl)}ethenyl groups as NLO-chromophores was synthesized and characterized. Polymer 7 was soluble in common organic solvents such as DMF and DMSO. It showed thermal stability up to 300°C in TGA with Tg value obtained from DSC near 134°C. The second harmonic generation (SHG) coefficient (d33) of poled polymer film at the 1,560nm fundamental wavelength was around 6.74×10-9 esu. The dipole alignment exhibited high thermal stability and there was no SHG decay below Tg due to the partial main-chain character of polymer structure, which was acceptable for NLO device applications. Copyright Taylor & Francis Group, LLC.