1192944-48-1

Basic information

• Product Name: C₂₇H₂₆N₂
• Synonyms: C₂₇H₂₆N₂
• CAS NO: 1192944-48-1
• Molecular Weight: 378.517
• Mol File: 1192944-48-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₂₇H₂₆N₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₂₆N₂(1192944-48-1)
• EPA Substance Registry System: C₂₇H₂₆N₂(1192944-48-1)

Safety Data

• Hazardous Substances Data: 1192944-48-1(Hazardous Substances Data)

Upstream product

• 29841-69-8 (S,S)-1,2-diphenyl-1,2-diaminoethane 
• 29180-98-1 2-bromo-4-methyl-1,1'-biphenyl 

Downstream Products

• 1192953-89-1 C₃₆H₃₆N₂ 

Relevant articles and documents

Improvements and Applications of the Transition Metal-Free Asymmetric Allylic Alkylation using Grignard Reagents and Magnesium Alanates

Two new N-heterocyclic carbene (NHC) ligands have been synthesized and employed in the transition metal-free asymmetric allylic alkylation (AAA) mediated by Grignard reagents and magnesium alanates. The employment of these ligands showed high yields and improved regio- and enantioselectivity in the formation of tertiary and quaternary stereocenters. Moreover, the low catalyst loading (up to 0.3 mol%) and high scalability (up to 10 mmol) of this improved methodology provide a convenient access to biologically active compounds and synthetically valuable intermediates.