1193731-95-1

Basic information

• Product Name: C₁₈H₁₀F₁₂O₂P^(1-)*C₂₄H₂₀P⁽¹⁺⁾
• Synonyms: C₁₈H₁₀F₁₂O₂P^(1-)*C₂₄H₂₀P⁽¹⁺⁾
• CAS NO: 1193731-95-1
• Molecular Weight: 856.627
• Mol File: 1193731-95-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₁₀F₁₂O₂P^(1-)*C₂₄H₂₀P⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₁₀F₁₂O₂P^(1-)*C₂₄H₂₀P⁽¹⁺⁾(1193731-95-1)
• EPA Substance Registry System: C₁₈H₁₀F₁₂O₂P^(1-)*C₂₄H₂₀P⁽¹⁺⁾(1193731-95-1)

Safety Data

• Hazardous Substances Data: 1193731-95-1(Hazardous Substances Data)

Upstream product

• 2065-67-0 tetraphenylphosphonium iodide 
• 77121-88-1 (S)-3,3,3',3'-tetrakis(trifluoromethyl)-1,1'-spirobi<3H,2,1λ⁵-benzoxaphosphole> 
• 1193731-94-0 C₈H₂₀N⁽¹⁺⁾*C₁₈H₁₀F₁₂O₂P^(1-) 

Relevant articles and documents

Umpolung of a hydrogen atom of water by using a hexacoordinated phosphate and its application to deuteride reduction reactions of carbonyl compounds

(Figure Presented) The polarity of a chemical bond is an important factor that determines the reactivity because a reaction of a positively charged atom with a negatively charged atom easily occurs. We report here a method for reversing the polarity of a hydrogen atom of water, which meant conversion of a protic hydrogen (H(δ+)) to a hydridic hydrogen (H(δ-)), by using a hexacoordinated phosphorus species. The method enables a reductive deuteration of carbonyl compounds utilizing inexpensive and easily usable D2O under mild conditions. The umpolung of a hydrogen atom was achieved by utilizing tautomerization of phosphorus compounds. Classical metal hydrides never have this function, and these results demonstrated the potential utility of nonmetallic compounds for umpolung of a hydrogen atom.