119388-39-5

Basic information

• Product Name: (Z)-3-hydroxy-1-(2-hydroxyphenyl)but-2-en-1-one
• Synonyms: (Z)-3-hydroxy-1-(2-hydroxyphenyl)but-2-en-1-one
• CAS NO: 119388-39-5
• Molecular Weight: 178.188
• Mol File: 119388-39-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-3-hydroxy-1-(2-hydroxyphenyl)but-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3-hydroxy-1-(2-hydroxyphenyl)but-2-en-1-one(119388-39-5)
• EPA Substance Registry System: (Z)-3-hydroxy-1-(2-hydroxyphenyl)but-2-en-1-one(119388-39-5)

Safety Data

• Hazardous Substances Data: 119388-39-5(Hazardous Substances Data)

Upstream product

• 16636-62-7 1-(2'-hydroxyphenyl)butane-1,3-dione 
• 118-93-4 o-hydroxyacetophenone 
• 75-36-5 acetyl chloride 
• 7250-94-4 o-acetoxyacetophenone 

Relevant articles and documents

INFLUENCE OF INTRAMOLECULAR HYDROGEN BONDS ON THE TAUTOMERIC EQUILIBRIUM OF 1,3-DIKETONES

The paper deals with a quantitative characterization of the influence of multiple intramolecular hydrogen bonds on the tautomeric equilibrium of 1,3-diketones by means of NMR-spectroscopy.The contents of the keto- and two enol forms of 1-(o-hydroxyphenyl)-1,3-butandione and 1-(o-methoxyphenyl)-1,3-butandione in tetrachloromethane, deuterochloroforme, acetone-d6 and acetonitrile-d3 are compared.The intramolecular hydrogen bond between the phenolic hydroxyl group and the aromatic carbonyl group in 1-(o-hydroxyphenyl)-1,3-butandione shifts the keto-enol equilibrium toward the keto-tautomer and enol-enol equilibrium toward the tautomer with an enolized aliphatic carbonyl group.

A Baker-Venkataraman retro-Claisen cascade delivers a novel alkyl migration process for the synthesis of amides

A simple extension of the carbamoyl Baker-Venkataraman rearrangement has been developed. If residual water in the reaction is not strictly excluded a Baker-Venkataraman retro-Claisen cascade takes place, giving amide products, in which an alkyl group apparently migrates between two functionalities of the substrate.