119450-35-0

Basic information

• Product Name: (E)-1-acetoxy-4-(phenylthio)-2-butene
• CAS NO: 119450-35-0
• Molecular Weight: 222.308
• Mol File: 119450-35-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-acetoxy-4-(phenylthio)-2-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-acetoxy-4-(phenylthio)-2-butene(119450-35-0)
• EPA Substance Registry System: (E)-1-acetoxy-4-(phenylthio)-2-butene(119450-35-0)

Safety Data

• Hazardous Substances Data: 119450-35-0(Hazardous Substances Data)

Upstream product

• 34414-28-3 (E)-1-chloro-4-acetoxybut-2-ene 
• 108-98-5 thiophenol 

Downstream Products

• 85250-56-2 (trans-Oct-2-enyl) phenyl sulfide 
• 113446-72-3 3-((phenylthio)methyl)-1-heptene 
• 119450-40-7 2-((2E,6E)-5-Benzenesulfonyl-tricosa-2,6-dienyl)-malonic acid dimethyl ester 
• 119450-41-8 (4E,8E)-7-Benzenesulfonyl-pentacosa-4,8-dienoic acid methyl ester 
• 119450-39-4 Acetic acid (2E,6E)-5-benzenesulfonyl-tricosa-2,6-dienyl ester 
• 119450-42-9 (4E,8E)-7-Benzenesulfonyl-pentacosa-4,8-dien-1-ol 
• 119450-37-2 [((E)-Nonadec-2-ene)-1-sulfonyl]-benzene 
• 119450-36-1 [((E)-Nonadec-2-enyl)sulfanyl]-benzene 

Relevant articles and documents

The use of metal reagents in stereo- and regioselective functionalizations of conjugated dienes

Conjugated dienes have been selectively functionalized via 1-acetoxy-4-chloro-2-alkenes and via 2-(phenylsulfonyl)-1,3-dienes.In both these approaches nucleophiles can be added to the 1- and 4-positions.It was shown that also non-stabilized carbon nucleophiles (from cuprates or copper(I)-catalyzed Grignard reactions) can be used.The utility of the functionalizations was demonstrated by the syntheses of a marine natural product and a butterfly pheromone.Finally, the 2-(phenyl-sulfonyl)-1,3-dienes show a dual electron demand in Diels-Alder reactions and give cycloadducts with both electron-rich and electron-deficient olefins.