119784-90-6

Basic information

• Product Name: 5-(1-methyl-2-propenylthio)-1-phenyl-1H-tetrazole
• CAS NO: 119784-90-6
• Molecular Weight: 232.309
• Mol File: 119784-90-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-(1-methyl-2-propenylthio)-1-phenyl-1H-tetrazole(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(1-methyl-2-propenylthio)-1-phenyl-1H-tetrazole(119784-90-6)
• EPA Substance Registry System: 5-(1-methyl-2-propenylthio)-1-phenyl-1H-tetrazole(119784-90-6)

Safety Data

• Hazardous Substances Data: 119784-90-6(Hazardous Substances Data)

Upstream product

• 6117-91-5 (E/Z)-2-buten-1-ol 
• 86-93-1 1-Phenyl-1H-tetrazole-5-thiol 
• 598-32-3 2-hydroxy-3-butene 
• 32276-00-9 S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate 

Relevant articles and documents

Ga(OTf)3-catalyzed direct substitution of alcohols with sulfur nucleophiles

It is reported that Ga(OTf)3 catalyzes the direct displacement of alcohols with sulfur nucleophiles. The products are versatile intermediates that can be utilized in carbon - carbon, carbon - sulfur bond formation or used in modified Julia olef

SINGLE-STEP PREPARATION OF ALLYLIC SULFIDES HAVING 1-PHENYLTETRAZOLE-5-THIO GROUP FROM ALLYLIC ALCOHOLS USING S,S'-BIS(1-PHENYL-1H-TETRAZOL-5-YL) DITHIOCARBONATE AND REACTIONS INVOLVING THE ALLYLIC SULFIDES

The reaction of allylic alcohols and S,S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate (1) gave allylic sulfides having 1-phenyltetrazole-5-thio group in a single step.Furthermore, these allylic sulfides could be applied to carbon-carbon bond and carbon-sulfur bond formations by using Grignard reagents or carbanions in the presence of catalytic amount of copper(I) bromide or palladium (0), respectively.