119934-45-1Relevant articles and documents
Mercuric dehydrogenations of N-tertiary piperidine derivatives with different substitution pattern
Moehrle, H.,Claas, M.
, p. 749 - 753 (2007/10/02)
A comparison of the dehydrogenation of different N-tertiary piperidine derivatives with mercuric EDTA and mercuric acetate shows an increase of the reaction with the complex method.This is especially evident with the N-demethylation of 1,2,2,6,6-pentamethylpiperidine.Generally with dehydrogenations offering a possibility of generating a tertiary or a secondary carbenium ion, the latter alternative is mostly also realized to a minor extent.