119993-20-3

Basic information

• Product Name: Glutamic acid, N-(phenylmethylene)-, dimethyl ester
• CAS NO: 119993-20-3
• Molecular Formula: C14H17NO4
• Molecular Weight: 263.293
• Mol File: 119993-20-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Glutamic acid, N-(phenylmethylene)-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Glutamic acid, N-(phenylmethylene)-, dimethyl ester(119993-20-3)
• EPA Substance Registry System: Glutamic acid, N-(phenylmethylene)-, dimethyl ester(119993-20-3)

Safety Data

• Hazardous Substances Data: 119993-20-3(Hazardous Substances Data)

Upstream product

• 23150-65-4 L-glutamic dimethyl ester hydrochloride 
• 100-52-7 benzaldehyde 
• 56-86-0 L-glutamic acid 
• 23150-65-4 dimethyl glutamate hydrochloride 
• 6525-53-7 glutamic acid dimethyl ether 
• 66646-88-6 (E)-N-benzylideneglycine methyl ester 
• 292638-85-8 acrylic acid methyl ester 
• 66646-88-6 methyl 2-(benzylideneamino)acetate 

Downstream Products

• 102841-30-5 2-{4-[(2,4-Diamino-pteridin-6-ylmethyl)-methyl-amino]-benzoylamino}-2-difluoromethyl-pentanedioic acid dimethyl ester 
• 95755-21-8 N-<4-<<(2,4-diamino-6-pteridinyl)methyl>methylamino>benzoyl>-2-difluoromethyl-glutamic acid 
• 102841-31-6 2-[4-(Benzyloxycarbonyl-methyl-amino)-benzoylamino]-2-difluoromethyl-pentanedioic acid dimethyl ester 
• 102841-29-2 2-Difluoromethyl-2-(4-methylamino-benzoylamino)-pentanedioic acid dimethyl ester 
• 95755-28-5 2-Difluoromethyl-5-oxo-pyrrolidine-2-carboxylic acid 
• 119993-32-7 dimethyl 1-methyl-t-5-phenyl-r-2,c-4-pyrrolidinedicarboxylate 
• 119993-32-7 dimethyl 1-methyl-c-5-phenyl-r-2,t-4-pyrrolidinedicarboxylate 
• 4931-66-2 methyl 5-oxopyrrolidine-2-carboxylate 
• 75516-84-6 dimethyl t-5-phenyl-r-2,c-4-pyrrolidinedicarboxylate 

Relevant articles and documents

Electroreductive intramolecular coupling of aromatic imino esters: Is four-membered cyclization much more favorable than six-membered cyclization?

The electroreduction of an aromatic imino ester prepared from (S)-glutamic acid in the presence of chlorotrimethylsilane and triethylamine afforded a four-membered cyclized product, a mixed ketal of cis-2,4-disubstituted azetidine-3-one, stereospecificall

Probing of the cis-5-phenyl proline scaffold as a platform for the synthesis of mechanism-based inhibitors of the Staphylococcus aureus sortase SrtA isoform

cis-5-Phenyl prolinates with electrophilic substituents at the fourth position of a pyrrolidine ring were synthesized by 1,3-dipolar cycloaddition of arylimino esters with divinyl sulfone and acrylonitrile. 4-Vinylsulfonyl 5-phenyl prolinates inhibit Staphylococcus aureus sortase SrtA irreversibly by modification of the enzyme Cys184 and could be used as hits for the development of antibacterials and antivirulence agents.

X=Y-ZH SYSTEMS AS POTENTIAL 1,3-DIPOLES. PART 17. SEQUENTIAL MICHAEL ADDITION-5-ENDO-TRIG CYCLISATION OF ARYLIDENE IMINES OF Α-AMINO ACID ESTERS

Imines of α-amino acid esters undergo regiospecific Michael addition to methyl acrylate or acrylonitrile in good yield in benzene at 25 degC catalysed by benzyltrimethylammonium methoxide (BTAM).The Michael adducts cyclise to a mixture of two stereoisomer