120085-98-5

Basic information

• Product Name: 2,9-bis(4-(dibromomethyl)phenyl)-1,10-phenanthroline
• Synonyms: 2,9-bis(4-(dibromomethyl)phenyl)-1,10-phenanthroline
• CAS NO: 120085-98-5
• Molecular Weight: 676.042
• Mol File: 120085-98-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,9-bis(4-(dibromomethyl)phenyl)-1,10-phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 2,9-bis(4-(dibromomethyl)phenyl)-1,10-phenanthroline(120085-98-5)
• EPA Substance Registry System: 2,9-bis(4-(dibromomethyl)phenyl)-1,10-phenanthroline(120085-98-5)

Safety Data

• Hazardous Substances Data: 120085-98-5(Hazardous Substances Data)

Upstream product

• 116287-98-0 2,9-bis-(4-methylphenyl)-1,10-phenanthroline 
• 2417-95-0 p-tolyllithium 
• 66-71-7 1,10-Phenanthroline 

Downstream Products

• 120085-99-6 2,9‐bis(4-formylphenyl)‐1,10‐phenanthroline 

Relevant articles and documents

Synthesis of new copper(I)-complexed rotaxanes via click chemistry

The Cu(I)-catalyzed dipolar cycloaddition of azides and terminal alkynes ('click' chemistry) has been used as a mild and efficient stoppering reaction for the preparation of new copper(I)-complexed rotaxanes.

Synthesis of bis-porphyrins containing a 2,9-diphenyl-1,10-phenanthroline spacer

The synthesis of bis-porphyrins disposed in an oblique fashion is described. The tetrapyrrole rings are linked via a 2,9-diphenyl-1,10-phenanthroline spacer. Two routes have been investigated: a step wise procedure and a direct strategy involving a double cyclisation step. From the bis-free base porphyrin, synthesized with an overall yield of 1% from 2,9-di(p-tolyl)-1,10-phenanthroline, an unsymmetrical zinc (II) porphyrin free base system was prepared and isolated in view of excited state energy and electron transfer.