1201898-91-0

Basic information

• Product Name: (R)-2-[1-(4-methoxyphenyl)-1-phenylethyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: (R)-2-[1-(4-methoxyphenyl)-1-phenylethyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1201898-91-0
• Molecular Weight: 338.255
• Mol File: 1201898-91-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-2-[1-(4-methoxyphenyl)-1-phenylethyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-[1-(4-methoxyphenyl)-1-phenylethyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1201898-91-0)
• EPA Substance Registry System: (R)-2-[1-(4-methoxyphenyl)-1-phenylethyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1201898-91-0)

Safety Data

• Hazardous Substances Data: 1201898-91-0(Hazardous Substances Data)

Upstream product

• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 133038-74-1 (S)-(-)-1-phenylethyl N,N-diisopropylcarbamate 
• 171364-79-7 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Enantioselective α-arylation of O-carbamates via sparteine-mediated lithiation and Negishi cross-coupling

A general and highly enantioselective arylation of carbamates derived from primary alcohols was developed by combining Hoppe's sparteine-mediated asymmetric lithiation with Negishi cross-coupling. Coupled with Aggarwal's lithiation-borylation sequence, the current method provides a short and divergent access to a variety of enantioenriched secondary and tertiary benzylic alcohols.