1202-32-0 Usage
Description
[(1E)-2-nitrobut-1-en-1-yl]benzene, with the molecular formula C10H11NO2, is an organic compound classified under the nitroalkenes. [(1E)-2-nitrobut-1-en-1-yl]benzene features a nitro group (-NO2) and an alkene group (-C=C-), and is composed of a benzene ring connected to a butenyl group with the nitro group attached to the alkene. Its unique structure and properties render it valuable for use in organic synthesis and various chemical and industrial processes. However, it is crucial to handle and store this chemical with care due to its potential health risks and adverse effects.
Uses
Used in Chemical and Industrial Processes:
[(1E)-2-nitrobut-1-en-1-yl]benzene is used as an intermediate in the synthesis of various organic compounds, contributing to the development of new materials and products in the chemical industry. Its reactivity and structural features make it a versatile building block for creating a wide range of molecules with different applications.
Used in Organic Synthesis:
As a key component in organic synthesis, [(1E)-2-nitrobut-1-en-1-yl]benzene is utilized as a starting material for the production of various pharmaceuticals, agrochemicals, and other specialty chemicals. Its unique combination of a nitro group and an alkene group allows for a range of reactions and transformations, leading to the creation of diverse chemical products.
Used in Research and Development:
In the field of research and development, [(1E)-2-nitrobut-1-en-1-yl]benzene serves as a valuable compound for studying the properties and reactivity of nitroalkenes. It can be used to explore new reaction mechanisms, develop innovative synthetic methods, and gain insights into the behavior of similar compounds.
Used in Pharmaceutical Industry:
[(1E)-2-nitrobut-1-en-1-yl]benzene is used as a building block for the development of new pharmaceuticals, particularly those targeting various diseases and conditions. Its unique structure allows for the creation of novel drug candidates with potential therapeutic benefits.
Used in Agrochemical Industry:
In the agrochemical industry, [(1E)-2-nitrobut-1-en-1-yl]benzene is employed as a starting material for the synthesis of new pesticides, herbicides, and other crop protection agents. Its properties and reactivity enable the development of more effective and environmentally friendly products for agricultural use.
Check Digit Verification of cas no
The CAS Registry Mumber 1202-32-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,2,0 and 2 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1202-32:
(6*1)+(5*2)+(4*0)+(3*2)+(2*3)+(1*2)=30
30 % 10 = 0
So 1202-32-0 is a valid CAS Registry Number.
1202-32-0Relevant articles and documents
Substrate promiscuity of ortho-naphthoquinone catalyst: Catalytic aerobic amine oxidation protocols to deaminative cross-coupling and n-nitrosation
Kim, Hun Young,Oh, Kyungsoo,Si, Tengda
, p. 9216 - 9221 (2019/10/08)
ortho-Naphthoquinone-based organocatalysts have been identified as versatile aerobic oxidation catalysts. Primary amines were readily cross-coupled with primary nitroalkanes via deaminative pathway to give nitroalkene derivatives in good to excellent yields. Secondary and tertiary amines were inert to ortho-naphthoquinone catalysts; however, secondary nitroalkanes were readily converted by ortho-naphthoquinone catalysts to the corresponding nitrite species that in situ oxidized the amines to the corresponding N-nitroso compounds. Without using harsh oxidants in a stoichiometric amount, the present catalytic aerobic oxidation protocol utilizes the substrate promiscuity feature to provide a facile access to amine oxidation products under mild reaction conditions.
Continuous-flow synthesis using a column reactor packed with heterogeneous catalysts: A convenient production of nitroolefins by using amino-functionalized silicagel
Ishitani, Haruro,Furiya, Yuichi,Kobayashi, Shū
supporting information, p. 6229 - 6232 (2017/09/30)
A continuous-flow synthesis of β-nitroolefins by using heterogeneous base catalysts has been developed. Although the use of an excess amount of nitro-donor such as nitromethane is required in conventional methods, nearly equimolar amounts of nitro-donors and carbonyl compounds are sufficient for high-yielding production of nitroolefins. Catalysts for this flow protocol are inexpensive and abundant, and high durability and high productivity were also realized by using an appropriate second support.
Iron-catalyzed tandem one-pot addition and cyclization of the blaise reaction intermediate and nitroolefins: Synthesis of substituted NH-pyrroles from nitriles
Zhao, Mi-Na,Liang, Hao,Ren, Zhi-Hui,Guan, Zheng-Hui
supporting information, p. 221 - 226 (2013/03/13)
The iron-catalyzed addition and cyclization of the Blaise reaction intermediate and nitroolefins to synthesize highly functionalized NH-pyrroles in a tandem one-pot manner from nitriles has been developed. This reaction shows good functional group tolerance and affords a broad spectrum of substituted NH-pyrroles in good yields. Copyright
