120383-84-8Relevant articles and documents
BENZYL- and 2- AND 4-NITROBENZYLCYCLOPROPANES AND THEIR REACTION WITH ORGANIC ACIDS
Fedotov, A. N.,Trofimova, E. V.,Mochalov, S. S.,Shabarov, Yu. S.
, p. 1272 - 1275 (2007/10/02)
The nitration of benzylcyclopropane and its transformations in organic acids were studied.Under the conditions of electrophilic nitration the small ring is preserved, while the ratio of the o- and p-nitrophenyl derivatives amounts to 1.1:1.The reaction of benzylcyclopropane with formic and acetic acids takes place with the addition of the fragments of the acids at the 1,2-bond of the three-carbon ring; o- and p-nitrobenzylcyclopropanes do not react with formic and acetic acids, with trifluoroacetic acid they form trifluoroacetates, and in the case of the ortho-substituted isomer nucleophilic assistance from the nitro group is observed.
