120400-66-0Relevant articles and documents
Addition of silylated nucleophiles to α-oxoketenes
Dudognon, Yohan,Presset, Marc,Rodriguez, Jean,Coquerel, Yoann,Bugaut, Xavier,Constantieux, Thierry
, p. 3010 - 3013 (2016)
A general evaluation of silylated nucleophiles to intercept transient α-oxoketenes generated by microwave-assisted Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds is presented. Original scaffolds and synthetic intermediates are accessed in a rapid
A Very Simple Synthesis of α-Substituted β-Ketoamides
Cossy, J.,Belotti, D.,Thellend, A.,Pete, J. P.
, p. 720 - 721 (2007/10/02)
α-Substituted β-ketoamides were prepared in good yields by irradiation of a solution of 2-diazo-1,3-diketones, at 254 nm, in the presence of primary or secondary amines.