120410-78-8

Basic information

• Product Name: 2P(C₆H₅)3*2⁽¹³⁾C₂H₄O*Ir⁽¹⁺⁾=(P(C₆H₅)3)2Ir(⁽¹³⁾CH₂⁽¹³⁾CH₂O)2⁽¹⁺⁾
• CAS NO: 120410-78-8
• Molecular Weight: 808.864
• Mol File: 120410-78-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2P(C₆H₅)3*2⁽¹³⁾C₂H₄O*Ir⁽¹⁺⁾=(P(C₆H₅)3)2Ir(⁽¹³⁾CH₂⁽¹³⁾CH₂O)2⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: 2P(C₆H₅)3*2⁽¹³⁾C₂H₄O*Ir⁽¹⁺⁾=(P(C₆H₅)3)2Ir(⁽¹³⁾CH₂⁽¹³⁾CH₂O)2⁽¹⁺⁾(120410-78-8)
• EPA Substance Registry System: 2P(C₆H₅)3*2⁽¹³⁾C₂H₄O*Ir⁽¹⁺⁾=(P(C₆H₅)3)2Ir(⁽¹³⁾CH₂⁽¹³⁾CH₂O)2⁽¹⁺⁾(120410-78-8)

Safety Data

• Hazardous Substances Data: 120410-78-8(Hazardous Substances Data)

Upstream product

• 84508-46-3 <1,2-13C2>ethylene oxide 

Relevant articles and documents

Solid-state chemistry of molecular metal oxide clusters. Reactions of microporous [(Ph3P)2IrH2]3PW12O 40 with small organic molecules

The heterogeneous reactions of [(Ph3P)2IrH2]3PW12O 40 with CO, PF3, C2H4, C2H2, CH3CH=CH2, c-C5H8, C6H6, CH3C6H5, 2,3-dimethyl-1,3-butadiene, isoprene, butadiene, Me3SiH, C2F4, CF3CF=CF2, CF2=CFCl, CH3C(O)H, ethylene oxide, CH3OH, and H2O are described. The chemistry can be described in terms of either addition of iridium to a substrate C-H bond to form intermediates that may optionally eliminate H2 or addition of Ir-H to a C=C bond. It is proposed that these reactants gain access to essentially all of the iridium sites by dissolving in the hydrophobic regions of the lattice of the low surface area iridium oxometalate.