1204393-81-6

Basic information

• Product Name: C₁₄H₁₃BO₂
• Synonyms: C₁₄H₁₃BO₂
• CAS NO: 1204393-81-6
• Molecular Weight: 224.067
• Mol File: 1204393-81-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₃BO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₃BO₂(1204393-81-6)
• EPA Substance Registry System: C₁₄H₁₃BO₂(1204393-81-6)

Safety Data

• Hazardous Substances Data: 1204393-81-6(Hazardous Substances Data)

Upstream product

• 556-96-7 5-bromo-1,3-xylene 
• 13826-27-2 2,2'-bis(1,3,2-benzodioxaborole) 

Downstream Products

• 325142-93-6 2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Syntheses of (4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)arenes through Pd-catalyzed borylation of arylbromides with the successive use of 2,2′-bis(1,3,2-benzodioxaborole) and pinacol

Syntheses of (4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)arenes through the Pd-catalyzed borylation of arylbromides with the successive use of 2,2′-bis(1,3,2-benzodioxaborole) and pinacol were investigated. PdCl 2(dppf) and AcOK in EtOH or DMSO successfully provided (4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)arenes. In particular, this method was more effective in the borylation of arylbromides bearing sulfonyl groups than the conventional Pd-catalyzed borylation using pinacolborane or bis(pinacolato)diboron.