120445-46-7

Basic information

• Product Name: (E)-2-(2-methylbenzylidene)hydrazine-1-carboxamide
• Synonyms: (E)-2-(2-methylbenzylidene)hydrazine-1-carboxamide
• CAS NO: 120445-46-7
• Molecular Weight: 177.206
• Mol File: 120445-46-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-2-(2-methylbenzylidene)hydrazine-1-carboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(2-methylbenzylidene)hydrazine-1-carboxamide(120445-46-7)
• EPA Substance Registry System: (E)-2-(2-methylbenzylidene)hydrazine-1-carboxamide(120445-46-7)

Safety Data

• Hazardous Substances Data: 120445-46-7(Hazardous Substances Data)

Upstream product

• 7055-03-0 2-methyl-N-phenylbenzamide 
• 4426-72-6 hydrazine carboxamide 
• 529-20-4 2-methylphenyl aldehyde 
• 552-45-4 1-chloromethyl-2-methylbenzene 
• 932-31-0 ortho-tolylmagnesium bromide 
• 118-90-1 ortho-methylbenzoic acid 
• 563-41-7 semicarbazide hydrochloride 
• 53724-30-4 o-Methyl-dithiobenzoesaeure 
• 110-86-1 pyridine 

Downstream Products

• 529-20-4 2-methylphenyl aldehyde 
• 32832-95-4 2-benzylbenzaldehyde 

Relevant articles and documents

Semicarbazide: A Transient Directing Group for C(sp3)?H Arylation of 2-Methylbenzaldehydes

Semicarbazide as an effective transient directing group for C(sp3)?H arylation of 2-methylbenzaldehydes is described. Various substituted 2-benzylbenzaldehydes are efficiently synthesized by this strategy. The salient features of this protocol are the use of inexpensive transient directing group, wide scope of substrates with good functional group compatibility, up to 98% yield, and applicability to gram scale. (Figure presented.).