1207273-31-1Relevant articles and documents
Thioether S-ligation in a side-on μ-η2:η2- peroxodicopper(ii) complex
Park, Ga Young,Lee, Yunho,Lee, Dong-Heon,Woertink, Julia S.,Narducci Sarjeant,Solomon, Edward I.,Karlin, Kenneth D.
supporting information; experimental part, p. 91 - 93 (2010/04/01)
[(ANS)CuI(CH3CN)]+ reacts with O 2 giving [{(ANS)CuII}2(μ-η2: η2-O22-)]2+, νO-O = 731 cm-1, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O22- binding.