1207286-38-1

Basic information

• Product Name: 1,1-dimethyl-1-(2-hydroxypropyl)amine benzoylformimide
• Synonyms: 1,1-dimethyl-1-(2-hydroxypropyl)amine benzoylformimide
• CAS NO: 1207286-38-1
• Molecular Weight: 250.298
• Mol File: 1207286-38-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,1-dimethyl-1-(2-hydroxypropyl)amine benzoylformimide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dimethyl-1-(2-hydroxypropyl)amine benzoylformimide(1207286-38-1)
• EPA Substance Registry System: 1,1-dimethyl-1-(2-hydroxypropyl)amine benzoylformimide(1207286-38-1)

Safety Data

• Hazardous Substances Data: 1207286-38-1(Hazardous Substances Data)

Upstream product

• 15206-55-0 methyl 2-oxo-2-phenylacetate 
• 57-14-7 N,N-Dimethylhydrazine 
• 75-56-9 methyloxirane 

Downstream Products

• 108-16-7 1-methyl-2-N,N-dimethylaminoethanol 
• 4461-33-0 benzoyl isocyanate 
• 1253263-44-3 C₁₅H₂₀N₂O₄ 
• 860223-18-3 2,3-dihydroxy-2,3-diphenyl-succinic acid diamide 

Relevant articles and documents

Aminimides derived from benzoylformic acid esters as thermally latent base catalysts

As a novel thermal latent anionic initiator for lower temperature applications, a new class of aminimide, 1,1-dimethyl-1-(2-hydroxypropyl)amine benzoylformimide (BFI), was synthesized from benzoylformic acid methyl ester in 95% yield, and its thermal rearrangement behavior was studied in detail. Thermal rearrangement of BFI proved to take place on heating above 80 °C via the Curtius rearrangement mechanism, generating the corresponding isocyanate, hydroxyamine, and their further reaction products. BFI proved to catalyze the polymerization of epoxides and epoxide/thiol system on heating above 80 °C. They exhibit both the long pot life and the low-temperature rapid polymerization in the presence of BFI which supported the promising applications of BFI as an efficient thermal latent base catalyst for anionically polymerizable/curable systems.