120823-76-9

Basic information

• Product Name: trimethyl(5-nitro-2-furyl)silane
• Synonyms: trimethyl(5-nitro-2-furyl)silane
• CAS NO: 120823-76-9
• Molecular Weight: 185.255
• Mol File: 120823-76-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trimethyl(5-nitro-2-furyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl(5-nitro-2-furyl)silane(120823-76-9)
• EPA Substance Registry System: trimethyl(5-nitro-2-furyl)silane(120823-76-9)

Safety Data

• Hazardous Substances Data: 120823-76-9(Hazardous Substances Data)

Upstream product

• 1578-33-2 2-furyltrimethylsilane 

Relevant articles and documents

Reactions of trialkyl(2-furyl)germanes with electrophilic reagents

The metallation (n-BuLi), alkylation (t-BuOH/H+), nitration (NO2+ BF4-), bromination (NBS, dioxane dibromide (DDB)), acylation and chlorination (chloramine T) reactions of (2-furyl)germanes were studied.Except for alkylation and bromination with DDB, the reactions involved electrophilic substitution of hydrogen atoms in position 5 or 3 of the furan ring.The alkylation reaction and bromination with DDB occur via ipso-substitution of the trialkylgermyl group.Dichlorocarbene generated by phase-transfer catalysis adds to the 2-germyl-substituted furan at the C4=C5 bond in the ring.Some of the above reactions were conducted with trimethyl(2-furyl)silane and 2-(t-butyl)furan, the silicon and carbon analogues of furylgermanes.The reactivities of the title compounds were compared.