1208864-96-3

Basic information

• Product Name: (S)-2-[(4-methoxyphenyl)-phenyl-trimethylsilyloxy-methyl]-pyrrolidine
• CAS NO: 1208864-96-3
• Molecular Weight: 355.552
• Mol File: 1208864-96-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-[(4-methoxyphenyl)-phenyl-trimethylsilyloxy-methyl]-pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-[(4-methoxyphenyl)-phenyl-trimethylsilyloxy-methyl]-pyrrolidine(1208864-96-3)
• EPA Substance Registry System: (S)-2-[(4-methoxyphenyl)-phenyl-trimethylsilyloxy-methyl]-pyrrolidine(1208864-96-3)

Safety Data

• Hazardous Substances Data: 1208864-96-3(Hazardous Substances Data)

Upstream product

• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 77581-28-3 (S)-proline-N-ethyl carbamate methyl ester 
• 100-58-3 phenylmagnesium bromide 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Relevant articles and documents

Enantioselective michael addition to α,β-Unsaturated aldehydes: Combinatorial catalyst preparation and screening, reaction optimization and mechanistic studies

Shortcut to chiral catalysts: An efficient combinatorial strategy based on back reaction screening by ESI-MS allows rapid evaluation of organocatalysis for the asymmetric Michael addition to α,β-unsaturated aldehydes (see scheme). An unexpected nonlinear effect has been observed in this reaction, resulting from a double nucleophilic-electrophilic activation mechanism involving two catalyst molecules "Chemical Equation Presented"