120906-16-3

Basic information

• Product Name: 1-allyl-2-(bromomethyl)benzene
• Synonyms: 1-allyl-2-(bromomethyl)benzene
• CAS NO: 120906-16-3
• Molecular Weight: 211.101
• Mol File: 120906-16-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-allyl-2-(bromomethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-allyl-2-(bromomethyl)benzene(120906-16-3)
• EPA Substance Registry System: 1-allyl-2-(bromomethyl)benzene(120906-16-3)

Safety Data

• Hazardous Substances Data: 120906-16-3(Hazardous Substances Data)

Upstream product

• 84801-07-0 2-(prop-2-enyl)benzyl alcohol 

Downstream Products

• 1067908-29-5 ethyl 2-(2-allylbenzyl)-3-oxobutanoate 
• 1067908-25-1 2-(2-allylbenzyl)-1,3-diphenylpropane-1,3-dione 
• 1067908-27-3 3-(2-allylbenzyl)pentane-2,4-dione 
• 1067908-31-9 2-(2-allylbenzyl)-1-phenylbutane-1,3-dione 
• 2177-47-1 2-Methylindene 
• 68846-65-1 2-methylene-2,3-dihydro-1H-indene 

Relevant articles and documents

Carbonylative Coupling of Alkyl Zinc Reagents with Benzyl Bromides Catalyzed by a Nickel/NN2 Pincer Ligand Complex

An efficient catalytic protocol for the three-component assembly of benzyl bromides, carbon monoxide, and alkyl zinc reagents to give benzyl alkyl ketones is described, and represents the first nickel-catalyzed carbonylative coupling of two sp3-carbon fragments. The method, which relies on the application of nickel complexed with an NN2-type pincer ligand and a controlled release of CO gas from a solid precursor, works well with a range of benzylic bromides. Mechanistic studies suggest the intermediacy of carbon-centered radicals.