12091-80-4

Basic information

• Product Name: Chromium, tricarbonyl(4-methyl[1,1'-biphenyl]-4-yl)-
• CAS NO: 12091-80-4
• Molecular Formula: C16H12CrO3
• Molecular Weight: 304.265
• Mol File: 12091-80-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Chromium, tricarbonyl(4-methyl[1,1'-biphenyl]-4-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Chromium, tricarbonyl(4-methyl[1,1'-biphenyl]-4-yl)-(12091-80-4)
• EPA Substance Registry System: Chromium, tricarbonyl(4-methyl[1,1'-biphenyl]-4-yl)-(12091-80-4)

Safety Data

• Hazardous Substances Data: 12091-80-4(Hazardous Substances Data)

Upstream product

• 1271-54-1 bis(benzene)chromium⁽⁰⁾ 
• 644-08-6 4-Methylbiphenyl 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 12082-05-2 (η6-fluorobenzene)tricarbonylchromium 
• 5720-05-8 4-methylphenylboronic acid 

Relevant articles and documents

Palladium catalysed cross-coupling of (fluoroarene)tricarbonyl-chromium(o) complexes

(Fluoroarene)tricarbonylchromium(o) complexes were found to undergo Suzuki and Stille cross-coupling reactions to form functionalised biaryl and styrene complexes in up to 87 and 52% yields, respectively. The Suzuki reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium carbonate in DME at reflux. The Stille reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium fluoride in DME at reflux and neither was adversely affected by a methoxy group on the complexed ring. The Suzuki reaction tolerated a chloro group on the arylboronic acid ring but not a bromo group. The Royal Society of Chemistry 2000.