12108-11-1 Usage
Description
(pi-aniline)tricarbonylchromium is a chemical compound that consists of a chromium atom complexed with three carbonyl groups and one pi-aniline ligand. It is a coordination complex with a unique structure and properties that make it useful in organic synthesis and catalysis. The pi-aniline ligand provides additional stabilization to the complex, allowing for the formation of stable coordination compounds with chromium.
Uses
Used in Organic Synthesis:
(pi-aniline)tricarbonylchromium is used as a reagent for facilitating various organic transformations. Its unique structure and properties enable it to participate in a range of chemical reactions, making it a valuable tool in the synthesis of complex organic molecules.
Used in Catalysis:
(pi-aniline)tricarbonylchromium is used as a catalyst in different chemical reactions. Its ability to form stable coordination compounds with chromium makes it an effective catalyst for promoting specific reaction pathways and enhancing the overall efficiency of the process.
Used in Research and Development:
(pi-aniline)tricarbonylchromium is used as a subject of study in the field of chemistry, particularly in the areas of coordination chemistry and organometallic chemistry. Its unique structure and potential applications make it an interesting compound for researchers to explore and understand its properties and reactivity.
Used in Pharmaceutical Industry:
(pi-aniline)tricarbonylchromium may potentially be used as a catalyst or intermediate in the synthesis of pharmaceutical compounds. Its unique properties and reactivity could be harnessed to develop new drugs or improve the synthesis of existing ones.
Used in Material Science:
(pi-aniline)tricarbonylchromium could be utilized in the development of new materials with specific properties, such as catalysts for specific reactions or components in advanced materials with unique characteristics. Its coordination chemistry properties make it a promising candidate for further exploration in this field.
Check Digit Verification of cas no
The CAS Registry Mumber 12108-11-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,2,1,0 and 8 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 12108-11:
(7*1)+(6*2)+(5*1)+(4*0)+(3*8)+(2*1)+(1*1)=51
51 % 10 = 1
So 12108-11-1 is a valid CAS Registry Number.
12108-11-1Relevant articles and documents
Matrix effects and their role in the low-temperature photochemistry of (η-Aniline)Cr(CO)3
Alamiry, Mohammed H.,Long, Conor,Fidgeon, Padraig P.,Pryce, Mary T.
, p. 1634 - 1640 (2010)
The low-temperature chemistry and photochemistry of (η6- Aniline)Cr(CO)3 was investigated by matrix isolation techniques in frozen CH4 or N2. The spectroscopic properties of the matrix changed both during the de
A laser flash photolysis, matrix isolation, and DFT investigation of (η6-C6H5Y)Cr(CO)3 (Y = NH2, OCH3, H, CHO, or CO2CH3)
Alamiry, Mohammed A.H.,Brennan, Peter,Long, Conor,Pryce, Mary T.
, p. 2907 - 2914 (2008)
The quantum yield for arene displacement from (η6-C6H5Y)Cr(CO)3 was measured in 1,1,2-trifluorotrichloroethane (Y = NH2, OCH3, H, CHO, or CO2CH3). Values of 0.24, 0.27, 0.15, 0.17, and 0.32 were obtained respectively (λexc. = 355 nm). These values are significantly higher than those measured for photoinduced arene loss in hydrocarbon solvents using the same excitation wavelength. Laser flash photolysis of (η6-C6H5Y)Cr(CO)3 in 1,1,2-trifluorotrichloroethane (λexc. = 355 nm) resulted in the rapid formation (6. Matrix isolation experiments on (η6-C6H5Y)Cr(CO)3 (Y = H or CHO) at 12 K in CH4 or CO-doped CH4 matrixes using monochromatic irradiation confirmed the presence of two discrete excited states, one leading to CO-loss and the other to arene-loss. The results correlate with the calculated electron drift in the excited state derived from density functional theory and time dependent density functional theory calculations.
THE CONFORMATIONS OF SOME MONO-SUBSTITUTED DERIVATIVES OF (η6-BENZENE)TRICARBONYLCHROMIUM(0) FROM DIPOLE MOMENT AND ELECTRIC BIREFRINGENCE STUDIES
Aroney, M. J.,Cooper, M. K.,Englert, P. A.,Pierens, R. K.
, p. 99 - 108 (2007/10/02)
Experimental dipole moments and molar Kerr constants (at 589 nm) are reported for (η6-C6H5Y)Cr(CO)3, where Y=CHO, COCH3, COOCH3, OCH3, NH2, N(CH3)2 and NH(CH3), examined as solutes in dioxan at 298 K.Analysis of these data in conjunction with i
