121122-22-3

Basic information

• Product Name: dichloro(N,N-dimethyl-3-diphenylphosphinopropylamine)platinum(II)
• CAS NO: 121122-22-3
• Molecular Weight: 537.328
• Mol File: 121122-22-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dichloro(N,N-dimethyl-3-diphenylphosphinopropylamine)platinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: dichloro(N,N-dimethyl-3-diphenylphosphinopropylamine)platinum(II)(121122-22-3)
• EPA Substance Registry System: dichloro(N,N-dimethyl-3-diphenylphosphinopropylamine)platinum(II)(121122-22-3)

Safety Data

• Hazardous Substances Data: 121122-22-3(Hazardous Substances Data)

Upstream product

• 14873-92-8 cis-dichlorobis(diethylsulfide)platinum(II) 
• 961-04-6 (γ-N,N-dimethylaminopropyl)diphenylphosphine 

Relevant articles and documents

A Study of the Generality of the Reaction of Diazomethane with Halogenoplatinum(II) Complexes in the Preparation of (Halogenomethyl)platinum(II) Complexes

Treatment of a range of platinum(II) halide (mainly chloride) complexes with diazomethane has been examined.Formation of both mono- and bis-halogenomethyl products has been observed.With one exception, methylene insertion appears to occur only when the metal-halogen bond is trans to a group of high trans influence (olefin, phosphine, isocyanide, alkyl, or hydride).With the trans-chlorohydrido derivatives investigated, the initially formed trans-(chloromethyl)hydrido products rearranged into the trans-(chloro)methyl species.Mechanisms of the methylene insertion and rearrangement processes are discussed.